Difference between revisions of "Coating oxide (chemical blacking) in surface industry"

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[[Image: Typical parameters of the process - Coating oxide (chemical blacking)
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{| border="1"
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| align="center" style="background:#2266CC;"|'''Process'''
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| align="center" style="background:#2266CC;"|'''Temperature [°C]'''
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| align="center" style="background:#2266CC;"|'''Heat transfer medium'''
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| align="center" style="background:#2266CC;"|'''Residence time'''
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| align="center" style="background:#2266CC;"|'''Chemicals'''
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| align="center" style="background:#2266CC;"|'''Concentration'''
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| align="center" style="background:#2266CC;"|'''Details'''
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| align="center" style="background:#2266CC;"|'''Literature'''
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|-
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| style="background:#AACCEE;"| Chemical blacking of steel|| align="center"| 121-149|| align="center"| || align=”center”| || align=”center”| Sodium hydroxide and sodium nitrate or a mixture of sodium nitrate and sodium nitrite ||  align="center"| Sodium hydroxide: 75 wt% and sodium nitrate: 25 wt%; sodium nitrate: 12 wt% and sodium nitrite: 13 wt%|| align="center"| || rowspan="6" align="center"| BAT for the surface treatment of metals and plastics, August 2006
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| rowspan="3" style="background:#AACCEE;"| Chemical blacking of stainless steel|| align="center"| 370|| align="center"| || align=”center”| || align=”center”| Molten sodium/porassium dichromate||  align="center"| || align="center"|
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| align="center"| 60-90|| align="center"| || align=”center”| || align=”center”| Chromic acid and sulphate||  align="center"| || align="center"| "Inox" process  
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| align="center"| 125-130|| align="center"| || align=”center”| || align=”center”| NaOH/NaNO2||  align="center"| || align="center"| Black colouring of chromium nickel steel
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| style="background:#AACCEE;"| Chemical blacking of copper|| align="center"| 93-100|| align="center"| || align=”center”| || align=”center”| Sodium hydroxide and sodium chlorite||  align="center"| Sodium hydroxide: 75 wt% and sodium chlorite: 25 wt%|| align="center"|
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| style="background:#AACCEE;"| Chemical blacking of brass|| align="center"| 93-100|| align="center"| || align=”center”| 5-10 min|| align=”center”| Sodium hydroxide and sodium chlorite||  align="center"| Sodium hydroxide: 85 wt% and sodium chlorite: 15 wt%|| align="center"|
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Revision as of 14:25, 1 December 2010

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  • Chemical blacking flowsheet


General flowsheet for the surface treatment of metals & plastics:


Chemical blacking flowsheet.jpg

Literature: BAT for the surface treatment of metals & plastics, 2006


  • Typical parameters of the process


Process Temperature [°C] Heat transfer medium Residence time Chemicals Concentration Details Literature
Chemical blacking of steel 121-149 Sodium hydroxide and sodium nitrate or a mixture of sodium nitrate and sodium nitrite Sodium hydroxide: 75 wt% and sodium nitrate: 25 wt%; sodium nitrate: 12 wt% and sodium nitrite: 13 wt% BAT for the surface treatment of metals and plastics, August 2006
Chemical blacking of stainless steel 370 Molten sodium/porassium dichromate
60-90 Chromic acid and sulphate "Inox" process
125-130 NaOH/NaNO2 Black colouring of chromium nickel steel
Chemical blacking of copper 93-100 Sodium hydroxide and sodium chlorite Sodium hydroxide: 75 wt% and sodium chlorite: 25 wt%
Chemical blacking of brass 93-100 5-10 min Sodium hydroxide and sodium chlorite Sodium hydroxide: 85 wt% and sodium chlorite: 15 wt%



  • Energy losses from the surface area of heated process solutions


Energy losses from the surface area of heated process solutions.jpg

LITERATURE: BAT for the Surface Treatment of Metals and Plastics, May 2005


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